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Royal fans have been sent into a frenzy after one of Princess Catherine's relatives were spotted with Queen Camilla this week. The Princess of Wales' brother, James Middleton, was all smiles on Tuesday as he attended a reception at Clarence House hosted by Queen Camilla.

The reception was in honour of cancer-detecting dogs trained by Medical Detection Dogs. The dogs are trained to sniff out signs of cancer in humans.

James was present at the event as his company, Ella & Co, donates treats for the dogs, who carry out life-saving work.

As Queen Camilla spotted James at the reception yesterday, they warmly greeted one another, with James giving Her Majesty a kiss on the cheek.

It is believed the Middletons are close with the Royal Family, and therefore it is likely James and the Queen would have spent plenty of time in each other's company before.

James uploaded some photographs from the event onto his Instagram account, writing: "Such an honour to be hosted by The Queen and witness some of the world's leading Medical Detection Dogs in action @medicaldetectiondogs.

"We heard about the Charity's incredible new AI-driven E-Nose technology. Data collected from these dogs is being used to train AI-powered "electronic noses" developed with Dr Andreas Mershin that can replicate canine diagnostics. Bio Detection Dogs are revolutionising early cancer screening. They're not just changing lives... they're saving them. James & Ella @ella.co are the official treat partner for MDD dogs in training."

Royal fans were sent into a frenzy at seeing James and Her Majesty together, with one fan commenting on Instagram: "This is wonderful."

Another said: "So lovely seeing you with the Queen."

Someone else wrote: "Aww, I love this!"

Another person commented: "What a dedicated and loving family the Middletons are."